Modern Fluoroorganic Chemistry: Synthesis, Reactivity, ApplicationsIn this handbook, Peer Kirsch clearly shows that this exciting field is no longer an exotic area of research. Aimed primarily at synthetic chemists wanting to gain a deeper understanding of the fascinating implications of including the highly unusual element fluorine in organic compounds, the main part of the book presents a wide range of synthetic methodologies and the experimental procedures selected undeniably show that this can be done with standard laboratory equipment. To round off, the author looks at fluorous chemistry and the applications of organofluorine compounds in liquid crystals, polymers and more besides. This long-awaited book represents an indispensable source of high quality information for everyone working in the field. |
Contents
| 1 | |
2 Synthesis of Complex Organofluorine Compounds | 25 |
3 Fluorous Chemistry | 171 |
4 Applications of Organofluorine Compounds | 203 |
Other editions - View all
Modern Fluoroorganic Chemistry: Synthesis, Reactivity, Applications Peer Kirsch No preview available - 2006 |
Modern Fluoroorganic Chemistry: Synthesis, Reactivity, Applications Peer Kirsch No preview available - 2004 |
Modern Fluoroorganic Chemistry: Synthesis, Reactivity, Applications Peer Kirsch No preview available - 2006 |
Common terms and phrases
Abstr acetonitrile aliphatic alkyl analogs Angew aromatic B. E. Smart bond carbocations carbon carbonyl catalyst cation CH 3 CH CH3 CH3 CH3CN chemical chiral compounds copper(I DAST difluorocarbene effect electron electronegative electrophilic electrophilic fluorination enol equivs Et2O ethers example F F F F F fluoride ion Fluorine Chem fluoroorganic fluorous G. A. Olah G. K. S. Prakash H H H hydrofluoric acid hydrogen inhibitor J. C. Tatlow kcal kcal molÀ1 Kirsch L. M. Yagupolskii Lewis acid liquid crystals Me3SiCF3 mechanism metabolic mixture mmol molecular nematic nucleophilic OH F OH OH olefins organic Organofluorine Chemistry oxidation perfluorinated perfluorocarbons phase polar PTFE pyridine R. D. Chambers R. E. Banks radical reaction reactivity reagents reflux Scheme silica gel solvent stabilization steric structure substituents substrates sulfur tetrafluoride Synthesis temperature Tetrahedron Lett trifluoromethyl