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Chapter 3 Stereoselective synthesis and transformation of siastatin B a novel glycosidase inhibitor directed toward new drugs for viral infection and t...
Chapter 4 The use of cyclic monoterpenoids as enantiopure starting materials in natural product synthesis
Chapter 5 Progress in the synthesis of iridoids and related natural products
Chapter 6 Stereoselective synthesis of brassinosteroids
Chapter 7 Organopalladium approaches to prostaglandins
Chapter 8 Transition metal organometallic methods for the synthesis of amino acids
Chapter 10 Recent progress in the synthesis of piperidine and indolizidine alkaloids
Chapter 11 Recent developments on the synthesis of aporphine alkaloids
Stereoselective syntheses of neolignans pterocarpans and several naturally occurring 2aryl23dihydrobenzofuran systems
Chapter 13 Biogenesislike transformation of 4substituted phenols by photooxygenation
Chapter 14 Furan in the synthesis of natural products
Chapter 15 Enantiomerically pure γbutyrolactones in natural products synthesis
Synthesis and application in asymmetric synthesis
Chapter 9 Palladiummediated synthesis of alkaloids
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Ac2O acetate acid AcOH actinobolin addition afforded aglycone alcohol aldehyde alkaloids alkylation allylic amine amino analogues brassinolide butenolide camphor carbonyl Chem Chemistry chiral chloride CO2Et CO2H CO2Me compounds converted CrO3 cyclization cycloaddition deprotection derived diastereomers DIBAL diol DMAP DMSO enol enone epoxide ester Et2O Et3N ether EtOH furan gave HMPA HOAc hydrogen hydrolysis hydroxyl indolizidine intermediate intramolecular isomer isomerization ketone lactam lactone LiAlH4 lithium m-CPBA Me2CO MeCN MeOH methyl mixture NaBH4 NaOH NaOMe natural products neuraminidase nucleophile OH OH OH olefin oxidation oxygen palladium piperidine quinone reaction reagent rearrangement reduction reflux ring room temp Scheme 25 shown in Scheme siastatin side chain sodium stereochemistry stereoselective substituent Swern oxidation synthesis t-BuOH Tetrahedron Lett treatment viii Y-butyrolactone yield
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