Tables of Chemical Kinetics: Homogeneous ReactionsU.S. Department of Commerce, National Bureau of Standards, 1951 - Chemistry |
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Page xviii
... value of the rate constant k is that calculated from the integrated equation with natural logarithms . Practically , numerical calculations are mostly made with the use of decimal logarithms , which amounts to a division of the true k ...
... value of the rate constant k is that calculated from the integrated equation with natural logarithms . Practically , numerical calculations are mostly made with the use of decimal logarithms , which amounts to a division of the true k ...
Page xix
... values of which are listed in the tables . It is not necessarily , and often quite certainly is not , the " rate law " of the reaction It could be a matter of choice ; the rate of an actually overall second - order reaction , first ...
... values of which are listed in the tables . It is not necessarily , and often quite certainly is not , the " rate law " of the reaction It could be a matter of choice ; the rate of an actually overall second - order reaction , first ...
Page xx
... values of k ° and n tabulated in adjacent columns , opposite the tempera- ture to which they refer . The symbol is the value of k in the order - of - magnitude unit 10 " , and must not be confused with any standard - state value ...
... values of k ° and n tabulated in adjacent columns , opposite the tempera- ture to which they refer . The symbol is the value of k in the order - of - magnitude unit 10 " , and must not be confused with any standard - state value ...
Page 44
... values of m and n ( k in sec1 ) : Catalyst HC1 0.1 Temperature 30 102m n 4.69 -4.17 M 4.39 -3.27 0.1 2 H2SO4 0.2 3 H2PO4 CH , C 1.0 CH COOH 1.0 8 8 8 8 60 3.93 60 3.74 -1.348 5.28 -2.580 60 6.21 -4.78 The rearrangement of the oxonium ...
... values of m and n ( k in sec1 ) : Catalyst HC1 0.1 Temperature 30 102m n 4.69 -4.17 M 4.39 -3.27 0.1 2 H2SO4 0.2 3 H2PO4 CH , C 1.0 CH COOH 1.0 8 8 8 8 60 3.93 60 3.74 -1.348 5.28 -2.580 60 6.21 -4.78 The rearrangement of the oxonium ...
Page 47
... values of a and b : Catalyst HC1 , HBr 。 OHC H COOH a b 9.11 × 10-4 1.27 × 10-3 7.60 x 10-6 2.63 × 10-4 H. Goldschmidt , R. W. Reinders , BDC 1896 , 29 , 1369 , 1899 ; H. Goldschmidt , S. Johnsen , E. Overwein , ZPC 1924 , 110 , 251 ...
... values of a and b : Catalyst HC1 , HBr 。 OHC H COOH a b 9.11 × 10-4 1.27 × 10-3 7.60 x 10-6 2.63 × 10-4 H. Goldschmidt , R. W. Reinders , BDC 1896 , 29 , 1369 , 1899 ; H. Goldschmidt , S. Johnsen , E. Overwein , ZPC 1924 , 110 , 251 ...
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Common terms and phrases
1950 Homogeneous Reaction 1950 Literature á á á acid action law Temperature addend Defined mass Aliphatic alkyl halide Amount of addend Amount of reactant aromatic Br₂ Bureau of Standards C_H_OH C. N. Hinshelwood C₂H CH CH CH COOH CH OH CH₂ CH₂OH CHCH CHCH CH CHOCH CHOH Cl₂ có có có COCH Comments Literature COOCH decomposition Defined mass action first-order H₂ H₂O H₂SO halogen Homogeneous Reaction Kinetics k AB 20 law Temperature kº law Temperature Liquid Liquid phase Amounts LITERATURE ¹ M/I per sec mass action law National Bureau National Research Council NO₂ Oxidant rate constants rate law reactant Addend Amount reactant Addend Catalyst reactant Defined mass Reaction Kinetics 212.471 Reaction Medium Solvent Reaction Solvent Amount Reaction type second-order SOLVOLYSIS Standards National Research Supplementary table Temperature Liquid phase که