Tables of Chemical Kinetics: Homogeneous ReactionsU.S. Department of Commerce, National Bureau of Standards, 1951 - Chemistry |
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Page xviii
... order rate constants the unit of concentration is immaterial , if rate and mass - action are in the same unit . Units of time and rate . Throughout these tables , the unit of time is the second , stated " unit of amount " ( mostly M / 1 ) ...
... order rate constants the unit of concentration is immaterial , if rate and mass - action are in the same unit . Units of time and rate . Throughout these tables , the unit of time is the second , stated " unit of amount " ( mostly M / 1 ) ...
Page xix
... second - order reaction , first - order in reactant A , and first - order in reactant B , normally to be represented by a mass - action function k AB , can be described by National Bureau of Standards - National Research Council XIX May ...
... second - order reaction , first - order in reactant A , and first - order in reactant B , normally to be represented by a mass - action function k AB , can be described by National Bureau of Standards - National Research Council XIX May ...
Page xx
... order function ' A on the understanding that [ B ] is included in k ' which , of course , will then vary with [ B ] ... degree ° C ) , are given occasionally under these headings . a Empirical rates , in the stated units of amount per second ...
... order function ' A on the understanding that [ B ] is included in k ' which , of course , will then vary with [ B ] ... degree ° C ) , are given occasionally under these headings . a Empirical rates , in the stated units of amount per second ...
Page 28
... second - order is more nearly constant throughout a run than the first - order k which falls off , particularly in HCl and HBr . With respect to the mass - action of the catalyst X , the order in acids is actually higher than first ...
... second - order is more nearly constant throughout a run than the first - order k which falls off , particularly in HCl and HBr . With respect to the mass - action of the catalyst X , the order in acids is actually higher than first ...
Page 176
... second order . For HCl - catalyzed hydrolysis , k ' was calculated assuming first order , from fractions of completion in , re- spectively , 120 , 120 , and 10 hours , with 0 , 0.03 , and 0.3 M / 1 HC1 ( 21b ) The values of k as listed ...
... second order . For HCl - catalyzed hydrolysis , k ' was calculated assuming first order , from fractions of completion in , re- spectively , 120 , 120 , and 10 hours , with 0 , 0.03 , and 0.3 M / 1 HC1 ( 21b ) The values of k as listed ...
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Common terms and phrases
1950 Homogeneous Reaction 1950 Literature á á á acid action law Temperature addend Defined mass Aliphatic alkyl halide Amount of addend Amount of reactant aromatic Br₂ Bureau of Standards C_H_OH C. N. Hinshelwood C₂H CH CH CH COOH CH OH CH₂ CH₂OH CHCH CHCH CH CHOCH CHOH Cl₂ có có có COCH Comments Literature COOCH decomposition Defined mass action first-order H₂ H₂O H₂SO halogen Homogeneous Reaction Kinetics k AB 20 law Temperature kº law Temperature Liquid Liquid phase Amounts LITERATURE ¹ M/I per sec mass action law National Bureau National Research Council NO₂ Oxidant rate constants rate law reactant Addend Amount reactant Addend Catalyst reactant Defined mass Reaction Kinetics 212.471 Reaction Medium Solvent Reaction Solvent Amount Reaction type second-order SOLVOLYSIS Standards National Research Supplementary table Temperature Liquid phase که