Tables of Chemical Kinetics: Homogeneous ReactionsU.S. Department of Commerce, National Bureau of Standards, 1951 - Chemistry |
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Page v
... acid anhydride + Alcohol ( 1 ) Bsterification ( liquid ) 11 Aliphatic carboxylic acid + Alcohol ( 19 ) Aromatic 11 + " Aliphatic alcohol + Hydrohalic acid ( 5 ) H polyalcohol + 11 ( 1 ) ( 8 ) 210 212 Ester Solvolysis ( liquid ) ...
... acid anhydride + Alcohol ( 1 ) Bsterification ( liquid ) 11 Aliphatic carboxylic acid + Alcohol ( 19 ) Aromatic 11 + " Aliphatic alcohol + Hydrohalic acid ( 5 ) H polyalcohol + 11 ( 1 ) ( 8 ) 210 212 Ester Solvolysis ( liquid ) ...
Page vi
... acid ( 3 ) Alkyl carboxylate + Hydrohalic acid ( 2 ) 222.471 222.741 230 CONDENSATION 232 Condensation ( liquid ) Aromatic aldehyde + Ketone ( 1 ) 232.446 C : N bond formation ( 10 ) 232.451 Aliphatic alcohol + Alkyl halide ( 4 ) ...
... acid ( 3 ) Alkyl carboxylate + Hydrohalic acid ( 2 ) 222.471 222.741 230 CONDENSATION 232 Condensation ( liquid ) Aromatic aldehyde + Ketone ( 1 ) 232.446 C : N bond formation ( 10 ) 232.451 Aliphatic alcohol + Alkyl halide ( 4 ) ...
Page x
... acid ester + Amine ( 1 ) 652.441 Aromatic " 1 + ( 1 ) 652.442 Alkyl halide + Aliphatic amine ( 5 ) 652.471 1 11 + Aromatic ม ( 9 ) 652.472 11 ( 1 ) 652.474 Aromatic " + 11 acyl halide + Aromatic amine ( 2 ) 652.476 Alkyl halide + ...
... acid ester + Amine ( 1 ) 652.441 Aromatic " 1 + ( 1 ) 652.442 Alkyl halide + Aliphatic amine ( 5 ) 652.471 1 11 + Aromatic ม ( 9 ) 652.472 11 ( 1 ) 652.474 Aromatic " + 11 acyl halide + Aromatic amine ( 2 ) 652.476 Alkyl halide + ...
Page 17
... acid . The c2 term arise from acid acting as proton acceptor . 40 % of the reaction ( 15 % in CH NO ) followed . 6 5 - may ( .9 ) Only ( . 11 .12 ) Accompanied by H - D exchange at the same rate . Ionic mechanism . ( .13 ) AS ( .8 ) The ...
... acid . The c2 term arise from acid acting as proton acceptor . 40 % of the reaction ( 15 % in CH NO ) followed . 6 5 - may ( .9 ) Only ( . 11 .12 ) Accompanied by H - D exchange at the same rate . Ionic mechanism . ( .13 ) AS ( .8 ) The ...
Page 28
... acids is actually higher than first ; this is attributed to catalysis by both the anion of the acid and the proton . With salts , the order with respect to the catalyst is actually first . The catalyzing proton donation is taken to be ...
... acids is actually higher than first ; this is attributed to catalysis by both the anion of the acid and the proton . With salts , the order with respect to the catalyst is actually first . The catalyzing proton donation is taken to be ...
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1950 Homogeneous Reaction 1950 Literature á á á acid action law Temperature addend Defined mass Aliphatic alkyl halide Amount of addend Amount of reactant aromatic Br₂ Bureau of Standards C_H_OH C. N. Hinshelwood C₂H CH CH CH COOH CH OH CH₂ CH₂OH CHCH CHCH CH CHOCH CHOH Cl₂ có có có COCH Comments Literature COOCH decomposition Defined mass action first-order H₂ H₂O H₂SO halogen Homogeneous Reaction Kinetics k AB 20 law Temperature kº law Temperature Liquid Liquid phase Amounts LITERATURE ¹ M/I per sec mass action law National Bureau National Research Council NO₂ Oxidant rate constants rate law reactant Addend Amount reactant Addend Catalyst reactant Defined mass Reaction Kinetics 212.471 Reaction Medium Solvent Reaction Solvent Amount Reaction type second-order SOLVOLYSIS Standards National Research Supplementary table Temperature Liquid phase که