Tables of Chemical Kinetics: Homogeneous ReactionsU.S. Department of Commerce, National Bureau of Standards, 1951 - Chemistry |
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Page 14
... ( CH ) CH 5 CH3COOH M / 1 0.9 HNO 1.19 k A 36.7 3 .7 1 - CH COCH ( CH3 ) C2H5 dioxane + D20 45.0 g / 100 ml 7.5 NaOD 0.43 35.0 ( 0.12 ) 3.05-4 ( 2 ) 4.94-4 ( 2 ) ( 5 ) 3600 ( 0.41 ) 11700 ( 0.65 ) 23400 .8 CH.COCH ( CH3 ) CH5 CH , C1 M ...
... ( CH ) CH 5 CH3COOH M / 1 0.9 HNO 1.19 k A 36.7 3 .7 1 - CH COCH ( CH3 ) C2H5 dioxane + D20 45.0 g / 100 ml 7.5 NaOD 0.43 35.0 ( 0.12 ) 3.05-4 ( 2 ) 4.94-4 ( 2 ) ( 5 ) 3600 ( 0.41 ) 11700 ( 0.65 ) 23400 .8 CH.COCH ( CH3 ) CH5 CH , C1 M ...
Page 15
... CH ( CH ) C2HICH CHC1 M / kg ( continued ) decalin 0.028 CHC12COOH 0.6 k AC 100 8.60 -6 ( 4 ) 0.4 8.30 -6 0.1 7.12 -6 0.6 2.57 -5 0.4 2.19 -5 0.1 1.43 -5 50504 11 .10 d - 5 CH CH COCH ( CH3 ) C2H5 CH COOH M / 1 0.9 HNO3 1.19 kA 25.0 ...
... CH ( CH ) C2HICH CHC1 M / kg ( continued ) decalin 0.028 CHC12COOH 0.6 k AC 100 8.60 -6 ( 4 ) 0.4 8.30 -6 0.1 7.12 -6 0.6 2.57 -5 0.4 2.19 -5 0.1 1.43 -5 50504 11 .10 d - 5 CH CH COCH ( CH3 ) C2H5 CH COOH M / 1 0.9 HNO3 1.19 kA 25.0 ...
Page 35
... CH : CHCOO Solvent Amount of reactant Addend Amount of addend Defined mass- action law Temperature Amounts are in M ... CH : CHCHCOO ̄ + H20 → L + OH ̄ . ( .2 ) ( .3 ) From the rate of establishment of the equilibrium CH CH CH : CHCOOCH ...
... CH : CHCOO Solvent Amount of reactant Addend Amount of addend Defined mass- action law Temperature Amounts are in M ... CH : CHCHCOO ̄ + H20 → L + OH ̄ . ( .2 ) ( .3 ) From the rate of establishment of the equilibrium CH CH CH : CHCOOCH ...
Page 37
... CH ( CH : CHCH ) C ( CH ) : C ( CN ) ( COOCH ) + ( CH ) , CHCH : C ( CH ) C ( CH : CHCH ) ( CN ) ( COOCH ) → pure liquid k A 180 3.54 -4 28.8 2.3 10 ( 2 ) 200 1.40 -3 As = -14.0 ( CH2 ) , CHCH ( CH2 : CHCH ) C ( CH ) : C ( CN ) ( COOCH ) .
... CH ( CH : CHCH ) C ( CH ) : C ( CN ) ( COOCH ) + ( CH ) , CHCH : C ( CH ) C ( CH : CHCH ) ( CN ) ( COOCH ) → pure liquid k A 180 3.54 -4 28.8 2.3 10 ( 2 ) 200 1.40 -3 As = -14.0 ( CH2 ) , CHCH ( CH2 : CHCH ) C ( CH ) : C ( CN ) ( COOCH ) .
Page 38
... CHCH : C ( С2H ) C ( CH : CHCH ) ( CN ) ( COOCH ) → pure liquid kA 176.5 1.53 -3 ( 1 ) CH , CH ( CH : CHCH2 ) C ( CH ) : C ( CN ) ( COOCH ) .7 CH2CH : C ( CH ) C ( CH2 : CHCH2 ) ( CN ) ; pure liquid kA 120 4.02 A ( 2 ) CH ̧CH ( CH : CHCH ) ...
... CHCH : C ( С2H ) C ( CH : CHCH ) ( CN ) ( COOCH ) → pure liquid kA 176.5 1.53 -3 ( 1 ) CH , CH ( CH : CHCH2 ) C ( CH ) : C ( CN ) ( COOCH ) .7 CH2CH : C ( CH ) C ( CH2 : CHCH2 ) ( CN ) ; pure liquid kA 120 4.02 A ( 2 ) CH ̧CH ( CH : CHCH ) ...
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Common terms and phrases
1950 Homogeneous Reaction 1950 Literature á á á acid action law Temperature addend Defined mass Aliphatic alkyl halide Amount of addend Amount of reactant aromatic Br₂ Bureau of Standards C_H_OH C. N. Hinshelwood C₂H CH CH CH COOH CH OH CH₂ CH₂OH CHCH CHCH CH CHOCH CHOH Cl₂ có có có COCH Comments Literature COOCH decomposition Defined mass action first-order H₂ H₂O H₂SO halogen Homogeneous Reaction Kinetics k AB 20 law Temperature kº law Temperature Liquid Liquid phase Amounts LITERATURE ¹ M/I per sec mass action law National Bureau National Research Council NO₂ Oxidant rate constants rate law reactant Addend Amount reactant Addend Catalyst reactant Defined mass Reaction Kinetics 212.471 Reaction Medium Solvent Reaction Solvent Amount Reaction type second-order SOLVOLYSIS Standards National Research Supplementary table Temperature Liquid phase که