Cinchona Alkaloids in Synthesis and Catalysis: Ligands, Immobilization and Organocatalysis
Choong Eui Song
John Wiley & Sons, Sep 3, 2009 - Science - 546 pages
This comprehensive review of cinchona-based chiralilty inducers and their applications covers every topic, including ligands, immobilization and organocatalysis. Each chapter summarizes the scope and limitations of the new methods and technologies, while the final chapter contains carefully selected working procedures of cinchona alkaloid-promoted reactions organized according to reaction type.
Invaluable reading for anyone wanting to learn about the current state of this hot topic.
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Ligands Immobilization and Organocatalysis Part One Cinchona Alkaloid Derivatives as Chirality Inducers in MetalCatalyzed Reactions
Ligands Immobilization and Organocatalysis Part Two Cinchona Alkaloid Derivatives as Chiral Organocatalysts
Ligands Immobilization and Organocatalysis Part Three Organic Chemistry of Cinchona Alkaloids
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a-keto a,b-unsaturated active adducts afforded alcohol aldehydes aldol alkene alkyl allyl amine ammonium analogues Angew aromatic aryl asymmetric synthesis base bifunctional carbon carbonyl Catal catalyst Chem chemistry Chen cinchona alkaloids cinchona PTCs cinchona-based cinchonidine cinchonine Cl Cl CO2Et compounds COOH COOMe Corey coworkers reported CSPs cyclic cycloaddition Deng derivatives desymmetrization diastereoselectivity dimeric ee Scheme ee values efficient electrophilic enantiomeric enantiomeric excess enantiomers enantioselectivity enantioseparation enolate enones epoxidation equiv esters ethyl Figure high enantioselectivity hydrogen bonding imines ketene ketones Lammerhofer Lectka Lindner Michael addition moiety nitrogen nucleophilic obtained optically organocatalysts oxidation Ph Ph phase-transfer presence protonation quinidine quinine quinuclidine racemic reaction reagents selectivity selector Sharpless solvent stereoselectivity steric substituted substrate synthesis synthetic t-Bu t-BuCQN temperature Tetrahedron Lett thiourea toluene vinyl Wang Wiley-VCH Verlag Wynberg yield